Gas absorption, gas diffusion and gas permeation

Sorption of gas in plastics for applications i such as packaging, electronics, and hydrogen storage is an important property. Gas sorption refers to the process by which a gas is absorbed into a solid. In plastics, gas absorption usually occurs due to interactions between the gas molecules and the polymer chains. These interactions can be based on various interactions, such as van der Waals forces (Debye or London type), or chemical reactions between the polymer and hydrogen molecules.

Gas absorption in plastics can have both positive and negative effects. On the positive side, for example, there is controlled gas permeability in food packaging or medical technology. Negative effects include changes in mechanical properties or optical transparency. In addition, certain gases, such as oxygen, can contribute to the degradation of plastics and thus reduce the service life of the material. Sorption is particularly important in the field of hydrogen storage.

A gas sorption balance is available at Fraunhofer LBF for gas sorption measurements, which enables measurements with various gases in a temperature range from 20 °C to 150 °C and a pressure range from 0 bar to 350 bar. The measured values and the material properties calculated from this help to characterize plastics and elastomers regarding their sorption properties and serve as input parameters for mathematical models and simulations.

Hydrogen application

In times where sustainability and environmentally friendly energy sources are crucial, research into innovative storage materials for hydrogen is becoming increasingly important. Hydrogen is considered a promising energy source as it only releases water during combustion and therefore causes no harmful emissions. However, to use hydrogen as an efficient and safe energy source, suitable storage methods must be developed.

The applications of thermosets or thermoplastics and elastomers in hydrogen storage are diverse. They are used in gas containers, tank systems, valves, seals, and O-rings to safely store hydrogen and protect it from leaks. Elastomers are the material of choice in sealing applications, for example in fuel cells or electrolyzers, to ensure their sealing function.

For the use of plastics in hydrogen environments, gas sorption, diffusion and permeation are generally of interest. These values must be known as a function of temperature and gas pressure in order to evaluate the suitability of materials or to carry out simulations and calculations. Various factors play a role in the gas absorption of hydrogen in elastomers and seals: the chemical composition and structure of the elastomers as well as additives and fillers influence the interaction with hydrogen molecules.

Publications:

  • J. H. Arndt, R. Brüll, T. Macko, P. Garg, J. C. J. F. Tacx, Characterization of the chemical composition distribution of polyolefin plastomers/elastomers (ethylene/1-octene copolymers) and comparison to theoretical predictions, Polymer 156 (2018) 214, DOI: 10.1016/j.polymer.2018.09.059
  • V. Dolle, A. Albrecht, R. Brüll, T. Macko, Characterisation of the Chemical Composition Distribution of LLDPE Using Interactive Liquid Chromatography, Macromol. Chem. Phys. 212 (2011) 959, DOI: 10.1002/macp.201000653
  • A. Albrecht, R. Brüll, T. Macko, F. Malz, H. Pasch, Comparison of High-Temperature HPLC, CRYSTAF and TREF for the Analysis of the Chemical Composition Distribution of Ethylene-Vinyl Acetate Copolymers, Macromol. Chem. Phys. 210 (2009) 1319, DOI: 10.1002/macp.200900135
  • A. Albrecht, R. Brüll, T. Macko, P. Sinha, H. Pasch, Analysing the Chemical Composition Distribution of Ethylene-Acrylate Copolymers: Comparison of HT-HPLC, CRYSTAF and TREF, Macromol. Chem. Phys. 209 (2008) 1909, DOI: 10.1002/macp.200800223